Product ID:0200002214 TAN, 59235 030050 413
MSDS Date:09/22/1999
FSC:8010
NIIN:00N092835
Status Code:A
MSDS Number: CJVQY

RAABE CORPORATION

MENOMONEE FALLS, WI 53052
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 414-255-9500

Cage: 0A3L4

RAABE CORPORATION THE PRECISION COLOR COMPANY

1090 MENOMONEE FALLS, WI 53051-1630 US

Telephone: 414-255-9500/800-966-7580

Cage: 0A3L4

1.80%.

CAS: 106-97-8

RTECS: EJ4200000

OSHA PEL 800 PPM

ACGIH TLV: 1900 MG/M3;800 PPM

2.20%.

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1800 MG/M3;1000 PPM

ACGIH TLV: 1000 PPM

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

1.00%.

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2.60%.

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 2400 MG/M3;1000 PPM

ACGIH TLV: 1780 MG/M3;750 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1.80%.

CAS: 78-93-3

RTECS: EL6475000

OSHA PEL 590 MG/M3;200 PPM

ACGIH TLV: 590 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1-METHOXY-2-ACETOXYPROPANE; (PROPYLENE GLYCOL METHYL ETHER

CAS: 108-65-6

RTECS: AI8925000

OSHA PEL N/K

ACGIH TLV: N/K

1.40%.

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL see Table Z-2

ACGIH TLV: 188 MG/M3;50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: MAY CAUSE SEV CORNEAL
INJURY IF LIQ COMES IN CONT W/EYES. SKIN: MAY CAUSE IRRIT. RPTD &
PRLNG CONT MAY CAUSE ALLERGIC DERM. INHAL: EXPOS TO HIGH CONCS OF
VAPS MAY CAUSE DIZZ, BRTHG DFCLTY , HDCH/RESP IRRIT. EXTREMELY HIGH
CONCS MAY CAUSE DROW, STAG, CONFUSION, UNCON, COMA/DEATH. LIQ/VAP
MAY BE IRRITATING TO SKIN, EYES, THROAT/LUNGS. INTENTIONAL MISUSE
BY DELIBERATELY CONCENTRATING & IN HALING CONTENTS CAN BE
HARMFUL/FATAL. INGEST: MOD TOX. MAY CAUSE STOM DISCOMFORT, NAUS,
VOMIT, DIARR, & NARCOSIS. ASPIR OF MATL INTO LUNGS IF SWALLOWED/IF
VOMIT OCCURS CAN CAUSE CHEM PNEUMIT WHICH CAN BE FATAL. (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS NO REPORTED
CARCINOGENS OR SUSPECTED CARCINOGENS.
Effects of Overexposure:HLTH HAZ: CHRONIC: CHRONIC OVEREXP TO A
COMPONENT/COMPONENTS IN THIS MATL HAS BEEN FOUND TO CAUSE THE
FOLLOWING EFTS IN LAB ANIMALS: KIDNEY DMG, EYE DMG, LUNG DMG, LIVER
DMG, SPLEEN DMG, ANEMIA, BRAIN DMG. CHRONIC OVEREXP TO A
COMPONENT/COMPONENTS IN THIS PROD HAS BEEN SUGGESTED AS A CAUSE OF
THE FOLLOWING EFTS IN HUMANS: LIVER DMG, CARD ABNORMS. RPTS HAVE
ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PER M BRAIN & NERV SYS DMG.
RPTD BRTHG/SKIN CONT OF METHYL ETHYL KETONE MAY INCR POTENCY OF
NEUROTOXINS SUCH AS HEXANE IF EXPOS OCCUR AT SAME TIME. RATS
EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVEL OPED LUNG
CANCER, HOWEVER, (SUP DAT)

First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER. GET MEDICAL
ATTENTION IF IRRITATION PERSISTS. FLUSH WITH LARGE QUANTITIES OF
WATER FOR AT LEAST 15 MINUTES. SKIN: WASH THOROUGHLY WITH SOAP &
WATER & SEEK MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHING.
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: MOVE PERSON
TO FRESH AIR. IF BREATHING STOPS, APPLY ARTIFICIAL RESPIRATION &
SEEK MEDICAL ATTE NTION. INGESTION: SINCE THIS PRODUCT MAY CONTAIN
MATERIALS WHICH CAN CAUSE LUNG DAMAGE IF ASPIRATED INTO LUNGS, THE
DECISION WHETHER TO INDUCE VOMITING OR NOT MUST BE MADE BY
PHYSICIAN AFTER CAREFUL C ONSIDERATION OF ALL MATERIALS INGESTED.

Flash Point:<-31.5C, -25.F
Lower Limits:1.0%
Upper Limits:13.1%
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE OR CHEMICAL FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . WATER SPRAY SHOULD NOT BE
USED EXCEPT TO KEEP DOWN VAPORS OR COOL CLOSED CONTAINERS TO
PREVENT BUILD-UP OF PRESSURE. IF WATER IS USED, FOG NOZZLES ARE
PREFERRED.
Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM
HEAT, SPARKS, & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. CONTENTS UNDER PRESS. DO NOT USE/STORE NEAR SOURCES
OF HEAT, SPARKS/OPEN FLAME. KEEP AWAY FROM ANY SOURCE OF HEAT SUCH
AS SUNLIGHT, HEATERS/STOVES THAT CAUSE CONTR TO BURST. (OTHER INFO)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID HEAT,
SPARKS, FLAMES AND ANYTHING WHICH COULD CAUSE FIRE. VENTILATE AREA
OF SPILL AND ADJACENT LOW LYING AREAS. AVOID BREATHING SOLVENT
VAPORS. REMOVE WITH INERT ABSORBENT MATERIALS AND NON-SPARKING
TOOLS.

Handling and Storage Precautions:STORE IN A COOL DRY AREA WITH
VENTILATION SUITABLE FOR STORING MATERIALS SHOWN IN INGREDIENTS
SECTION. KEEP AWAY FROM HEAT, SPARKS AND FLAME. STORE IN A COOL
PLACE AWAY FROM DIRECT SUNLIGHT OR ANY SOU RCE OF IGNITION. DO NOT
STORE AT TEMPERATURES ABOVE 120F.

Respiratory Protection:IF WORKPLACE EXPOSURE LIMITS ARE EXCEEDED FOR
ANY COMPONENT (SEE INGREDIENTS SECTION FOR HAZARDOUS COMPONENTS AND
EXPOSURE LIMITS), A NIOSH APPROVED RESPIRATOR SUITABLE FOR
COMPONENTS LISTED IS RECOMM ENDED.
Ventilation:SUFFICIENT VENTILATION, IN VOLUME AND PATTERN, SHOULD BE
PROVIDED TO KEEP AIR CONTAMINANT BELOW CURRENT APPLICABLE OSHA PEL
OR ACGIH'S TLV LIMIT.
Protective Gloves:CHEM RESIST PLASTIC/RUBBER GLOVES RECOMMENDED FOR
PROLONGED/REPEATED CONT.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . APPROPRIATE IMPERVIOUS CLOTHING IS RECOMMENDED IF
PROLONGED OR REPEATED CONTACT IS LIKELY.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING. SMOKE IN
DESIGNATED AREAS ONLY. WASH HANDS THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP: SUCH EXPOS LEVELS ARE NOT ATTAINABLE IN WORKPLACE
W/THIS MATL. PROD CONTAINS TOLUENE WHICH MAY BE HARMFUL TO FETUS
BASED ON ANIMAL STUDIES. RPTD EXPOS TO TOLUENE HAS BEEN ASSOC
W/HIGH FREQUENCY HEARING LOSS IN LAB ANIMALS. HUMAN CONSEQUENCES
OF THIS FINDING IS UNCERTAIN. (OTHER INFO)

Boiling Pt:>-17.2C, 1.F
B.P. Text:1F - 302F
Vapor Pres:5585.20 MM HG @ 20C
Spec Gravity:0.766
Evaporation Rate & Reference:7.700 (N-BUTYL ACETATE=1)

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID CONTACT WITH HEAT, SPARKS, AND OPEN
FLAME. PRODUCT MAY EXPLODE IF HEATED. KEEP COOL, AVOID EXPOSURE TO
HEAT.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON DIOXIDE, CARBON MONOXIDE, AND UNIDENTIFIED ORGANIC
MATERIALS.

Waste Disposal Methods:PLACE IN CLOSED CONTAINERS. DISPOSE OF PRODUCT
IN ACCORDANCE WITH LOCAL, COUNTY, STATE, AND FEDERAL REGULATIONS.

Toxicological Information:NO SPECIFIC INFORMATION IS AVAILABLE. PLEASE
REFER TO HEALTH HAZARDS SECTION FOR AVAILABLE INFORMATION ON
POTENTIAL HEALTH EFFECTS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO SPECIFIC ECOLOGICAL INFORMATION IS AVAILABLE FOR THIS
PRODUCT. --TRANSPORTATION INFORMATION: SEE 49 CFR 172.101,
HAZARDOUS MATERIALS TABLE 1 FOR MORE INFORMATION ON SHIPPING
HAZARDOUS MATERIALS ON LAND. SEE IATA DANGEROUS GOODS REGULATIONS
FOR MORE DETAILS ON SHIPPING HAZARDOUS MATERIALS BY AIR.

Transport Information:DOMESTIC GROUND SHIPMENT OF PAINT AEROSOLS & ALL
LIQ PAINT PRODS IN CONTRS OF 1 QUART/LESS: CONSUMER COMMODITY,
ORM-D. DOMESTIC AIR SHIPMENT OF PAINT AEROSOLS & ALL LIQ PAINT IN
CONTRS OF 1 QUART/LESS : CONSUMER COMMODITY, CLASS 9, ID 8000,
MISCELLANEOUS LABEL. INTERNATIONAL AIR SHIPMENT OF PAINT AEROSOLS:
AEROSOLS, FLAMM, N.O.S. CLASS 2.1, UN 1950, FLAMM GAS LABEL.
INTERNATIONAL AIR SHIPMENT OF LI Q PAINT IN CONTRS OF 1 QUART/LESS:
PAINT, CLASS 3, UN 1263, FLAMM LIQ LABEL. ALL SHIPMENTS OF LIQ
PAINT IN CONTRS OF MORE THAN 1 QUART: PAINT, CLASS 3, UN 1263,
PACKING GROUP II, FLAMM LIQ LABEL. (ECO LOGICAL INFO)

SARA Title III Information:SARA 313 INFORMATION: THIS PRODUCT CONTAINS
THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 4 0 CFR PART 372: XYLENE, CAS #
1330-20-7, 1.1320% BY WEIGHT; METHYL ETHYL KETONE, CAS # 78-93-3,
6.7280% BY WEIGHT; TOLUENE, CAS # 108-88-3, 9.6710% BY WEIGHT.
Federal Regulatory Information:FEDERAL REGULATIONS: TOXIC SUBSTANCES
CONTROL ACT: THE CHEMICAL SUBSTANCES IN THIS PRODUCT ARE LISTED ON
THE TSCA SECTION 8 INVENTORY. INTERNATIONAL REGULATIONS: CANADA:
THE CHEMICAL SUBSTANCES IN THI S PRODUCT ARE LISTED ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
State Regulatory Information:THIS PRODUCT CONTAINS CHEMICAL(S) WHICH
ARE LISTED ON CALIFORNIA'S PROPOSITION 65 LIST. IF THE PRODUCT IS
TO BE SOLD OR USED IN CALIFORNIA THE FOLLOWING WARNING STATEMENTS
MUST APPEAR ON THE LABEL: WA RNING! THIS PRODUCT CONTAINS A
CHEMICAL OR CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. NEW JERSEY RIGHT-TO-KNOW:
NO NON-HAZARDOUS INGREDIENTS ARE AMON G THE TOP FIVE INGREDIENTS.
PENNSYLVANIA RIGHT-TO-KNOW: NO NON-HAZARDOUS INGREDIENTS ARE
PRESENT AT GREATER THAN 3%.